In French, the plural they is the masculine ils for mixed gender groups, and only the feminine elles for groups that are exclusively feminine. On is a singular gender neutral form of they often used in situations with unknown gender.
I would use on for singular and ils for plural when talking about a non-binary person because that seems the most reasonable application of the language as I understand it.
However as a non-native speaker I would defer to whatever native speakers do. Can't say I know what the established best practice is.